4,159 research outputs found
Experimental evidence of thermal fluctuations on the X-ray absorption near-edge structure at the aluminum K-edge
After a review of temperature-dependent experimental x-ray absorption
near-edge structure (XANES) and related theoretical developments, we present
the Al K-edge XANES spectra of corundum and beryl for temperature ranging from
300K to 930K. These experimental results provide a first evidence of the role
of thermal fluctuation in XANES at the Al K-edge especially in the pre-edge
region. The study is carried out by polarized XANES measurements of single
crystals. For any orientation of the sample with respect to the x-ray beam, the
pre-edge peak grows and shifts to lower energy with temperature. In addition
temperature induces modifications in the position and intensities of the main
XANES features. First-principles DFT calculations are performed for both
compounds. They show that the pre-edge peak originates from forbidden 1s to 3s
transitions induced by vibrations. Three existing theoretical models are used
to take vibrations into account in the absorption cross section calculations:
i) an average of the XANES spectra over the thermal displacements of the
absorbing atom around its equilibrium position, ii) a method based on the crude
Born-Oppenheimer approximation where only the initial state is averaged over
thermal displacements, iii) a convolution of the spectra obtained for the atoms
at the equilibrium positions with an approximate phonon spectral function. The
theoretical spectra so obtained permit to qualitatively understand the origin
of the spectral modifications induced by temperature. However the correct
treatment of thermal fluctuation in XANES spectroscopy requires more
sophisticated theoretical tools
Value Iteration for Long-run Average Reward in Markov Decision Processes
Markov decision processes (MDPs) are standard models for probabilistic
systems with non-deterministic behaviours. Long-run average rewards provide a
mathematically elegant formalism for expressing long term performance. Value
iteration (VI) is one of the simplest and most efficient algorithmic approaches
to MDPs with other properties, such as reachability objectives. Unfortunately,
a naive extension of VI does not work for MDPs with long-run average rewards,
as there is no known stopping criterion. In this work our contributions are
threefold. (1) We refute a conjecture related to stopping criteria for MDPs
with long-run average rewards. (2) We present two practical algorithms for MDPs
with long-run average rewards based on VI. First, we show that a combination of
applying VI locally for each maximal end-component (MEC) and VI for
reachability objectives can provide approximation guarantees. Second, extending
the above approach with a simulation-guided on-demand variant of VI, we present
an anytime algorithm that is able to deal with very large models. (3) Finally,
we present experimental results showing that our methods significantly
outperform the standard approaches on several benchmarks
Topology of event distribution as a generalized definition of phase transitions in finite systems
We propose a definition of phase transitions in finite systems based on
topology anomalies of the event distribution in the space of observations. This
generalizes all the definitions based on the curvature anomalies of
thermodynamical potentials and provides a natural definition of order
parameters. The proposed definition is directly operational from the
experimental point of view. It allows to study phase transitions in Gibbs
equilibria as well as in other ensembles such as the Tsallis ensemble.Comment: 4 pages, 3 figure
Nuclear break-up of 11Be
The break-up of 11Be was studied at 41AMeV using a secondary beam of 11Be
from the GANIL facility on a 48Ti target by measuring correlations between the
10Be core, the emitted neutrons and gamma rays. The nuclear break-up leading to
the emission of a neutron at large angle in the laboratory frame is identified
with the towing mode through its characteristic n-fragment correlation. The
experimental spectra are compared with a model where the time dependent
Schrodinger equation (TDSE) is solved for the neutron initially in the 11 Be. A
good agreement is found between experiment and theory for the shapes of neutron
experimental energies and angular distributions. The spectroscopic factor of
the 2s orbital is tentatively extracted to be 0.46+-0.15. The neutron emission
from the 1p and 1d orbitals is also studied
Test of the Running of in Decays
The decay rate into hadrons of invariant mass smaller than
can be calculated in QCD assuming global
quark--hadron duality. It is shown that this assumption holds for
~GeV. From measurements of the hadronic mass distribution, the
running coupling constant is extracted in the range
0.7~GeV. At , the result is
. The running of is in good
agreement with the QCD prediction.Comment: 9 pages, 3 figures appended; shortened version with new figures, to
appear in Physical Review Letters (April 1996
Gamma-Ray Burst Sequences in Hardness Ratio-Peak Energy Plane
The narrowness of the distribution of the peak energy of
spectrum of gamma-ray bursts (GRBs) and the unification of GRB population are
great puzzles yet to be solved. We investigate the two puzzles based on the
global spectral behaviors of different GRB population in the
plane (HR the spectral hardness ratio) with BATSE and HETE-2 observations. It
is found that long GRBs and XRFs observed by HETE-2 seem to follow the same
sequence in the plane, with the XRFs at the low end of this
sequence. The long and short GRBs observed by BATSE follow significantly
different sequences in the plane, with most of the short GRBs
having a larger hardness ratio than the long GRBs at a given .
These results indicate that the global spectral behaviors of the long GRB
sample and the XRF sample are similar, while that of short GRBs is different.
The short GRBs seem to be a unique subclass of GRBs, and they are not the
higher energy extension of the long GRBs (abridged).Comment: 9 pages, 3 figure
Syzygies in equivariant cohomology for non-abelian Lie groups
We extend the work of Allday-Franz-Puppe on syzygies in equivariant
cohomology from tori to arbitrary compact connected Lie groups G. In
particular, we show that for a compact orientable G-manifold X the analogue of
the Chang-Skjelbred sequence is exact if and only if the equivariant cohomology
of X is reflexive, if and only if the equivariant Poincare pairing for X is
perfect. Along the way we establish that the equivariant cohomology modules
arising from the orbit filtration of X are Cohen-Macaulay. We allow singular
spaces and introduce a Cartan model for their equivariant cohomology. We also
develop a criterion for the finiteness of the number of infinitesimal orbit
types of a G-manifold.Comment: 28 pages; minor change
Preclinical Evaluation of Antitumor Efficacy of a New Radiopharmaceutical Based on Thermoresponsive Carrier and Samarium-153
This work is devoted to studying the in vivo antitumor efficacy of the new injection radiopharmaceutical based on thermoresponsive polymer and β−-emitting radionuclide samarium-153 (153Sm-KARP-CheM). The study of in vivo antitumor efficacy was performed using mice F1 and C57Bl/6 with transplanted subcutaneously sarcoma S37 and melanoma B16, respectively. The animals received single intratumoral bolus injections of 37 MBq (1 mCi), or 18.5 MBq (0.5 mCi) of 153Sm-KARP-CheM, or saline in a volume 0.1 ml. The efficacy of antitumortreatment was evaluated using tumor growth inhibition index (TGI, %) and increase of average life span (ILS, %). The most meaningful therapeutic efficacy after intratumoral injection of 153Sm-KARPCheM was observed in melanoma-bearing mice C57Bl/6. The highest values of TGI for melanoma B16 were 79.5% and 79.6% after treatment with 18.5 MBq or 37 MBq, respectively. An increase of average life span by 17.1% was found in group of melanoma-bearing mice treated with 37 MBq of 153Sm-KARP-CheM only. Tumor growth inhibition of sarcoma S37 was slightly lower as compared with melanoma B16: 62.5% and 59.0% in 37 MBq and 18.5 MBq groups, respectively. 153Sm-KARP-CheM didn’t increase average life span of treated animals. In conclusion, 153Sm-KARP-CheM seems to be effective radiopharmaceutical for local tumor radiotherapy.
Keywords: thermoresponsive polymer, samarium-153, radionuclide therapy of cancer, sarcoma S37, melanoma B16, antitumor efficacy
The OSACA Database and a Kinematic Analysis of Stars in the Solar Neighborhood
We transformed radial velocities compiled from more than 1400 published
sources, including the Geneva--Copenhagen survey of the solar neighborhood
(CORAVEL-CfA), into a uniform system based on the radial velocities of 854
standard stars in our list. This enabled us to calculate the average weighted
radial velocities for more than 25~000 HIPPARCOS stars located in the local
Galactic spiral arm (Orion arm) with a median error of +-1 km/s. We use these
radial velocities together with the stars' coordinates, parallaxes, and proper
motions to determine their Galactic coordinates and space velocities. These
quantities, along with other parameters of the stars, are available from the
continuously updated Orion Spiral Arm CAtalogue (OSACA) and the associated
database. We perform a kinematic analysis of the stars by applying an
Ogorodnikov-Milne model to the OSACA data. The kinematics of the nearest single
and multiple main-sequence stars differ substantially. We used distant
(r\approx 0.2 kpc) stars of mixed spectral composition to estimate the angular
velocity of the Galactic rotation -25.7+-1.2 km/s/kpc, and the vertex
deviation,l=13+-2 degrees, and detect a negative K effect. This negative K
effect is most conspicuous in the motion of A0-A5 giants, and is equal to
K=-13.1+-2.0 km/s/kpc.Comment: 16 pages, 8 figure
Measurements of hydrogen cyanide (HCN) and acetylene (C2H2) from the Infrared Atmospheric Sounding Interferometer (IASI)
Hydrogen cyanide (HCN) and acetylene (C2H2) are ubiquitous atmospheric trace gases with medium lifetime, which are frequently used as indicators of combustion sources and as tracers for atmospheric transport and chemistry. Because of their weak infrared absorption, overlapped by the CO2 Q branch near 720 cm−1, nadir sounders have up to now failed to measure these gases routinely. Taking into account CO2 line mixing, we provide for the first time extensive measurements of HCN and C2H2 total columns at Reunion Island (21° S, 55° E) and Jungfraujoch (46° N, 8° E) in 2009–2010 using observations from the Infrared Atmospheric Sounding Interferometer (IASI). A first order comparison with local ground-based Fourier transform InfraRed (FTIR) measurements has been carried out allowing tests of seasonal consistency which is reasonably captured, except for HCN at Jungfraujoch. The IASI data shows a greater tendency to high C2H2 values. We also examine a nonspecific biomass burning plume over austral Africa and show that the emission ratios with respect to CO agree with previously reported values
- …